12045-63-5

  • Product NameTitanium boride
  • Molecular FormulaB2Ti
  • Molecular Weight69.502
  • Purity99%
  • AppearanceGrey powder
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Product Details

Quick Details

  • CasNo: 12045-63-5
  • Molecular Formula: B2Ti
  • Appearance: Grey powder
  • Purity: 99%

Buy High Grade Titanium boride 12045-63-5 Export with Cheap Price

  • Molecular Formula:B2Ti
  • Molecular Weight:69.502
  • Appearance/Colour:Grey powder 
  • Melting Point:2900-3225 °C 
  • PSA:0.00000 
  • Density:4.52 g/mL at 25 °C(lit.) 
  • LogP:-1.83240 

TITANIUM BORIDE(Cas 12045-63-5) Usage

Chemical Properties

Titanium diboride (TiB2) a gray hexagonal crystal and It is a ceramic material with high hardness and strength, good thermal shock resistance, low resistance, and not easy to be corroded by molten metal.

Uses

Titanium boride is used in seals wear parts and cutting tools. It is used to make ballistic armour due to its high hardness. It is used to constitute composite materials in which the presence of the material serves to increase strength and fracture toughness of the matrix.

Application

Titanium diboride is a conductive composite material. Making conductive boron nitride (evaporation boat) with Titanium boride (TiB2) and boron nitride (BN) is the main component of vacuum aluminum plating equipment. It can also be used as an important component of multi-component composite materials. Titanium boride can be combined with TiC, TiN, SiC and other materials to form composite materials for cutting tools. It can also be used as a component to make armor protection materials. The best material for components and functional devices. TiB2 is used to metallurgical additive, high-temperature electrical conductor, refractory, cermet component, coatings resistant to attack by molten metals, aluminum manufacture, super alloys.Used as a cathode material in aluminum smelting and can be shaped by electrical discharge machining. Specialized applications in such areas as impact resistant armor, cutting tools, crucibles, neutron absorbers and wear resistant coatings.

Preparation

Synthesis of titanium diboride through reduction of titanium dioxide by boron carbide and carbon, and its reaction equation2TiO2+B4C+3C=2TiB2+4COVapor DepositionUsing TiCl4 and BCl3 as raw materials, with the participation of H2, the deposition temperature is 800 ~ 1000 ℃, abrasive-grade and electronic-grade products can be obtained. The reaction equationTiCl4+2BCl3+5H2=TiB2+10HCl

InChI:InChI=1/2B.Ti/rB2Ti/c1-3-2

12045-63-5 Relevant articles

Optimization and characterization of LPCVD TiB2 for ULSI applications

Choi,Ruggles,Osburn,Xing

, p. 3053 - 3061 (1991)

The chemical vapor deposition of TiB2 fr...

Effect of Ni content on the products of Ni-Ti-B system via self-propagating high-temperature synthesis reaction

Huang,Wang,Li,Yin,Jiang

, p. 286 - 291 (2008)

The effect of Ni content on the products...

Chemical and electrochemical behavior of titanium diboride in cryolite-alumina melt and in molten aluminum

Devyatkin,Kaptay

, p. 107 - 109 (2000)

Titanium diboride is the most perspectiv...

High critical current density of MgB2 bulk superconductor doped with Ti and sintered at ambient pressure

Zhao,Feng,Cheng,Zhou,Wu,Machi,Fudamoto,Koshizuka,Murakami

, p. 1154 - 1156 (2001)

Ti-doped MgB2 superconductors with diffe...

Preparation of TiB2 and ZrB2. Influence of a mechano-chemical treatment on the borothermic reduction of titania and zirconia

Millet,Hwang

, p. 351 - 355 (1996)

TiB2 and ZrB2 have been synthesized by a...

Low-temperature densification of TiN-TiB2 composites through reactive hot pressing with excess Ti additions

Rangaraj, Lingappa,Divakar, Canchi,Jayaram, Vikram

, p. 311 - 317 (2009)

Reactive hot pressing of Ti and BN powde...

Processing and properties of TiB2 with MoSi2 sinter-additive: A first report

Murthy,Basu,Balasubramaniam,Suri,Subramanian,Fotedar

, p. 131 - 138 (2006)

The densification of non-oxide ceramics ...

Determination of the thermodynamic stability of TiB2

Jain, Ashish,Pankajavalli,Anthonysamy,Ananthasivan,Babu,Ganesan,Gupta

, p. 747 - 752 (2010)

The standard free energy of formation of...

Effect of KCl, NaCl and CaCl2 mixture on volume combustion synthesis of TiB2 nanoparticles

Nekahi, Atiye,Firoozi, Sadegh

, p. 1377 - 1383 (2011)

Preparation of titanium diboride (TiB2) ...

Mechanochemical synthesis and pressureless sintering of TiB2-AlN composites

Kim, Hyung-Jong,Choi, Heon-Jin,Lee, June-Gunn

, p. 1022 - 1024 (2002)

TiB2-AlN composites have been fabricated...

Compositional and structural changes in TiB2 films induced by bias, in situ and post-deposition annealing, respectively

Pelleg, Joshua,Sade,Sinder,Mogilyanski

, p. 118 - 127 (2006)

Structural changes in TiB2 films were in...

Sn-flux syntheses, characterizations and bonding analyses of OsB and TiB2

Fokwa, Boniface P.T.,Misse, Patrick R.N.,Gille?en, Michael,Dronskowski, Richard

, p. 339 - 342 (2010)

Single-phase crystalline powder of the t...

Ball milling-induced combustion in powder mixtures containing titanium, zirconium, or hafnium

Takacs

, p. 75 - 84 (1996)

Ball milling induces self propagating hi...

A convenient solid-state reaction route to nanocrystalline TiB2

Shi, Liang,Gu, Yunle,Chen, Luyang,Yang, Zeheng,Ma, Jianhua,Qian, Yitai

, p. 192 - 194 (2004)

Nanocrystalline titanium diboride (TiB2)...

Influence of stearic acid on mechanochemical reaction between Ti and BN powders

Byun, Jung-Soo,Shim, Jae-Hyeok,Cho, Young Whan

, p. 149 - 156 (2004)

The influence of stearic acid as a proce...

Effects of TiC doping on the upper critical field of MgB2 superconductors

Yan,Zhou,Yan,Lu

, p. 1032 - 1035 (2008)

TiC doped MgB2 bulks were fabricated by ...

Mechanism of the cathode process in the electrochemical synthesis of TiB2 in molten salts. I. The synthesis in an all-fluoride electrolyte

Makyta,Matiasovsky,Taranenko

, p. 861 - 866 (1989)

The mechanism of the cathode process in ...

Growth inhibition to enhance conformal coverage in thin film chemical vapor deposition

Kumar, Navneet,Yanguas-Gil, Angel,Abelson, John R.,Daly, Scott R.,Girolami, Gregory S.

, p. 17660 - 17661 (2008)

-

Properties of titanium and zirconium diborides obtained by self-propagated high-temperature synthesis

Radev,Marinov

, p. 48 - 51 (1996)

Self-propagated high-temperature synthes...

In situ synthesis of ceramic composite materials in the Ti-B-C-N system by a mechanically induced self-sustaining reaction

Aviles, Miguel A.,Chicardi, Ernesto,Cordoba, Jose M.,Sayagues, Maria J.,Gotor, Francisco J.

, p. 2133 - 2139 (2012)

The synthesis of multicomponent ceramic ...

Properties of TiB2 powders obtained in a mechanochemical way

Radev,Klisurski

, p. 39 - 41 (1994)

Mechanochemical synthesis of TiB2 powder...

The effect of surface oxides during hot pressing of TiB2

Jensen, Morten Sundheim,Einarsrud, Mari-Ann,Grande, Tor

, p. 623 - 630 (2009)

Hot pressing of TiB2 has been investigat...

Simultaneous spark plasma synthesis and densification of TiC-TiB 2 composites

Locci, Antonio M.,Orru, Roberto,Cao, Giacomo,Munir, Zuhair A.

, p. 848 - 855 (2006)

The simultaneous synthesis and densifica...

A reduction-boronation route to nanocrystalline titanium diboride

Chen, Luyang,Gu, Yunle,Shi, Liang,Yang, Zeheng,Ma, Jianhua,Qian, Yitai

, p. 231 - 233 (2004)

Nanocrystalline titanium diboride (TiB2)...

In situ synthesis and properties of Ti3AlC2/TiB 2 composites

Li, Chao,Li, Meishuan,Zhou, Yanchun,Zhang, Jie,He, Lingfeng

, p. 3615 - 3620 (2007)

In order to improve the mechanical prope...

Effect of Cu content on the reaction behaviors of self-propagating high-temperature synthesis in Cu-Ti-B4C system

Liang,Wang,Yang,Zhao,Jiang

, p. 113 - 118 (2008)

The SHS reaction behaviors of the Cu-Ti-...

Morphology and deposition rates of TiB2 prepared by chemical vapour deposition of TiCl4 + B2H6 system

Mukaida,Goto,Hirai

, p. 1069 - 1075 (1990)

Titanium diboride (TiB2) is a promising ...

A facile one-step route to nanocrystalline TiB2 powders

Chen, Luyang,Gu, Yunle,Qian, Yitai,Shi, Liang,Yang, Zeheng,Ma, Jianhua

, p. 609 - 613 (2004)

Nanocrystalline titanium diboride (TiB2)...

PLASMA ENHANCED CHEMICAL VAPOR DEPOSITION OF TITANIUM DIBORIDE FILMS.

Williams

, p. 43 - 45 (1985)

Thin films of titanium borides were depo...

Structure of TiB2 produced by dynamic ion mixing

Riviere,Guesdon,Delafond,Denanot

, p. 477 - 486 (1988)

The technique of dynamic ion mixing is b...

Synthesis of nano-sized titanium diboride in a melt of anhydrous sodium tetraborate

Volkova,Shulga,Shilkin

, p. 819 - 821 (2012)

X-ray powder diffraction, scanning elect...

Electrochemical deposition of TiB2 in high temperature molten salts

Fastner,Steck,Pascual,Fafilek,Nauer

, p. 32 - 35 (2008)

The electrochemical deposition of TiB2 o...

Effect of titanium carbide addition on the thermoelectric properties of B4C ceramics

Cai,Nan,Paderno,McLachlan

, p. 523 - 526 (2000)

TiB2/B4C composite ceramics are prepared...

Preparation of titanium diboride nanopowder

Kravchenko,Torbov,Shilkin

, p. 614 - 616 (2010)

We have studied the reaction between NaB...

Reactive hot pressing of titanium nitride-titanium diboride composites at moderate pressures and temperatures

Rangaraj, Lingappa,Divakar, Canchi,Jayaram, Vikram

, p. 1872 - 1878 (2004)

Dense composites in the Ti-B-N system ha...

Preparation of TiB2 sintered compacts by hot pressing

Itoh, Hideaki,Naka, Shigeharu,Matsudaira, Tsuneaki,Hamamoto, Hiroshi

, (1990)

A sintered compact of titanium diboride ...

Electrochemical synthesis of TIB2 layers out of FLiNaK electrolyte in the presence of TaCl5 additive

Rybakova,Babushkina,Artner,Nauer

, p. D593-D599 (2010)

TiB2 coatings on Mo substrates were elec...

Low temperature electrical resistivity studies and search for superconductivity in Ti-B system

Kutty,Pillai,Karunakaran,Vaidya

, p. 1123 - 1126 (1989)

Resistivity of TiBx alloy has been measu...

Effect of HCl concentration on TiB2 separation from a self-propagating high-temperature synthesis (SHS) product

Demircan, Umut,Derin, Bora,Yücel, Onuralp

, p. 312 - 318 (2007)

This paper presents a synthesis of TiB2 ...

Formation of titanium nitride by mechanical milling and isothermal annealing of titanium and boron nitride

Ding,Yao,Qiu,Bai,Guo,Xue,Wang,Zhou,Su

, p. 77 - 81 (2005)

The formation of titanium nitride with r...

Acid leaching of SHS produced magnesium Oxide/titanium diboride

Lok, Jonathan Y.,Logan, Kathryn V.,Payyapilly, Jairaj J.

, p. 26 - 31 (2009)

The stoichiometric self-propagating high...

Consolidation of combustion-synthesized titanium diboride-based materials

Hoke,Meyers

, p. 275 - 284 (1995)

The quasi-static consolidation in uniaxi...

Synthesis of ultrafine titanium diboride particles by rapid carbothermal reduction in a particulate transport reactor

Saito, Takeyasu,Fukuda, Tomoyuki,Maeda, Hideaki,Kusakabe, Katsuki,Morooka, Shigeharu

, p. 3933 - 3938 (1997)

Ultrafine TiB2 powders were synthesized ...

Synthesis of TiB2 by electric discharge assisted mechanical milling

Calka,Oleszak

, p. 346 - 348 (2007)

In this study, synthesis of titanium dib...

Reaction control of TiB2 formation from titanium metal and amorphous boron

Itoh,Matsudaira,Naka,Hamamoto

, p. 420 - 424 (1989)

TiB2 powder was synthesized by a control...

A mild solvothermal route to nanocrystalline titanium diboride

Gu, Yunle,Qian, Yitai,Chen, Luyang,Zhou, Fu

, p. 325 - 327 (2003)

Titanium diboride (TiB2) has been synthe...

Homogeneous TiB2 ceramics achieved by electric current-assisted self-propagating reaction sintering

Salamon, David,Eriksson, Mirva,Nygren, Mats,Shen, Zhijian

, p. 3303 - 3306 (2007)

Using spark plasma sintering techniques,...

New criteria for the applicability of combustion synthesis: The investigation of thermodynamic and kinetic processes for binary Chemical Reactions

Tan, Xiaoming,Su, Xianli,Yan, Yonggao,Uher, Ctirad,Zhang, Qingjie,Tang, Xinfeng

supporting information, (2021/01/07)

Combustion synthesis is a novel techniqu...

Novel sustainable silicothermic synthesis of phase-pure TiB2 fine powder

Ke, Changming,Ni, Yue'e,Qin, Zhi,Wang, Jingran,Zhang, Jinhua

, (2020/04/28)

Phase pure TiB2 powder of 100–400 nm was...

Sequence of phase evolution during mechanically induced self-propagating reaction synthesis of TiB and TiB2via magnetically controlled ball milling of titanium and boron powders

Oghenevweta,Wexler,Calka

, p. 380 - 391 (2017/02/05)

Mechanically induced self-propagating re...

Influence of friction stir processing on microstructure and properties of AA7075/TiB2 in situ composite

Rajan, H.B. Michael,Dinaharan,Ramabalan,Akinlabi

, p. 250 - 260 (2015/11/09)

Friction stir processing (FSP) is a nove...

12045-63-5 Process route

boron trichloride
10294-34-5

boron trichloride

titanium tetrachloride
7550-45-0

titanium tetrachloride

titanium diboride
12045-63-5

titanium diboride

titanium(III) chloride
7705-07-9

titanium(III) chloride

Conditions
Conditions Yield
With hydrogen; In gas; byproducts: HCl; Irradiation (UV/VIS); in a laser powder synthesis cell; 1100°C; X-ray diffraction; transmission electron microscopy; single point BET surface area analysis; thermal gravimetric analysis; differential thermalanalysis; atomic absorption spectroscopy;
0%
titanium tetrachloride
7550-45-0

titanium tetrachloride

diborane
19287-45-7

diborane

titanium diboride
12045-63-5

titanium diboride

titanium(III) chloride
7705-07-9

titanium(III) chloride

Conditions
Conditions Yield
In gas; Irradiation (UV/VIS); in a laser powder synthesis cell; 1330-1530°C; various yields for various conditions; X-ray diffraction; transmission electron microscopy; single point BET surface area analysis; thermal gravimetric analysis; differential thermalanalysis; atomic absorption spectroscopy;
50-70

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