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This invention solves the problem of pro...
PROBLEM TO BE SOLVED: To provide a manuf...
The present invention provides a method ...
The present invention relates to a proce...
oct-1-ene
n-perfluorohexyl iodide
1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodotetradecane
1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane
Conditions | Yield |
---|---|
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; In N,N-dimethyl-formamide; for 12h; Overall yield = 56 %; Irradiation;
|
oct-1-ene
n-perfluorohexyl iodide
1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane
Conditions | Yield |
---|---|
With tris-(trimethylsilyl)silane; oxygen; In water; at 20 ℃; for 36h; Inert atmosphere;
|
71% |
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; In N,N-dimethyl-formamide; for 12h; Irradiation;
|
45% |
Multi-step reaction with 2 steps
1: 1,1,2,2-tetrafluoroethyl-2,2,2-trifluoroethyl ether; diisopropyl peroxydicarbonate / 88 - 100 °C / Large scale
2: palladium 10% on activated carbon; sodium acetate; hydrogen / methanol / Large scale
With diisopropyl peroxydicarbonate; palladium 10% on activated carbon; 1,1,2,2-tetrafluoroethyl-2,2,2-trifluoroethyl ether; hydrogen; sodium acetate; In methanol;
|
oct-1-ene
perfluoro-n-hexyl chloride
1-bromo-1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane
n-perfluorohexyl iodide
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